High-conductance pathways in ring-strained disilanes by qay of direct σ-Si–Si to Au coordination
Kim NT, Li H, Venkataraman L, Leighton JL. 2016. High-conductance pathways in ring-strained disilanes by qay of direct σ-Si–Si to Au coordination. Journal of the American Chemical Society. 138(36), 11505–11508.
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Journal Article
| Published
| English
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Author
Kim, Nathaniel T.;
Li, Haixing;
Venkataraman, LathaISTA 
;
Leighton, James L.
;
Leighton, James L.Abstract
A highly conducting electronic contact between a strained disilane and Au is demonstrated through scanning tunneling microscope-based single-molecule measurements. Conformationally locked cis diastereomers of bis(sulfide)-anchor-equipped 1,2-disilaacenaphthenes readily form high-conducting junctions in which the two sulfide anchors bind in a bipodal fashion to one gold electrode, providing enough stability for a stable electrical contact between the Si–Si σ bond and the other electrode.
Publishing Year
Date Published
2016-08-26
Journal Title
Journal of the American Chemical Society
Publisher
American Chemical Society
Volume
138
Issue
36
Page
11505-11508
ISSN
eISSN
IST-REx-ID
Cite this
Kim NT, Li H, Venkataraman L, Leighton JL. High-conductance pathways in ring-strained disilanes by qay of direct σ-Si–Si to Au coordination. Journal of the American Chemical Society. 2016;138(36):11505-11508. doi:10.1021/jacs.6b07825
Kim, N. T., Li, H., Venkataraman, L., & Leighton, J. L. (2016). High-conductance pathways in ring-strained disilanes by qay of direct σ-Si–Si to Au coordination. Journal of the American Chemical Society. American Chemical Society. https://doi.org/10.1021/jacs.6b07825
Kim, Nathaniel T., Haixing Li, Latha Venkataraman, and James L. Leighton. “High-Conductance Pathways in Ring-Strained Disilanes by Qay of Direct σ-Si–Si to Au Coordination.” Journal of the American Chemical Society. American Chemical Society, 2016. https://doi.org/10.1021/jacs.6b07825.
N. T. Kim, H. Li, L. Venkataraman, and J. L. Leighton, “High-conductance pathways in ring-strained disilanes by qay of direct σ-Si–Si to Au coordination,” Journal of the American Chemical Society, vol. 138, no. 36. American Chemical Society, pp. 11505–11508, 2016.
Kim NT, Li H, Venkataraman L, Leighton JL. 2016. High-conductance pathways in ring-strained disilanes by qay of direct σ-Si–Si to Au coordination. Journal of the American Chemical Society. 138(36), 11505–11508.
Kim, Nathaniel T., et al. “High-Conductance Pathways in Ring-Strained Disilanes by Qay of Direct σ-Si–Si to Au Coordination.” Journal of the American Chemical Society, vol. 138, no. 36, American Chemical Society, 2016, pp. 11505–08, doi:10.1021/jacs.6b07825.
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