Oxidation potentials correlate with conductivities of aromatic molecular wires
Quinn JR, Foss FW, Venkataraman L, Breslow R. 2007. Oxidation potentials correlate with conductivities of aromatic molecular wires. Journal of the American Chemical Society. 129(41), 12376–12377.
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Journal Article
| Published
| English
Scopus indexed
Author
Quinn, Jordan R.;
Foss, Frank W.;
Venkataraman, LathaISTA
;
Breslow, Ronald

Abstract
Cyclic voltammetry determines first and second oxidation potentials of conducting diamines. The results show that unsubstituted and methyl-substituted molecules conduct electricity in partially positively charged states, reflecting electron delocalization at the wire−gold junctions, but with electron-withdrawing substituents, the molecular wires are closer to uncharged as conductors, consistent with HOMO arguments.
Publishing Year
Date Published
2007-09-22
Journal Title
Journal of the American Chemical Society
Publisher
American Chemical Society
Volume
129
Issue
41
Page
12376-12377
ISSN
eISSN
IST-REx-ID
Cite this
Quinn JR, Foss FW, Venkataraman L, Breslow R. Oxidation potentials correlate with conductivities of aromatic molecular wires. Journal of the American Chemical Society. 2007;129(41):12376-12377. doi:10.1021/ja0745097
Quinn, J. R., Foss, F. W., Venkataraman, L., & Breslow, R. (2007). Oxidation potentials correlate with conductivities of aromatic molecular wires. Journal of the American Chemical Society. American Chemical Society. https://doi.org/10.1021/ja0745097
Quinn, Jordan R., Frank W. Foss, Latha Venkataraman, and Ronald Breslow. “Oxidation Potentials Correlate with Conductivities of Aromatic Molecular Wires.” Journal of the American Chemical Society. American Chemical Society, 2007. https://doi.org/10.1021/ja0745097.
J. R. Quinn, F. W. Foss, L. Venkataraman, and R. Breslow, “Oxidation potentials correlate with conductivities of aromatic molecular wires,” Journal of the American Chemical Society, vol. 129, no. 41. American Chemical Society, pp. 12376–12377, 2007.
Quinn JR, Foss FW, Venkataraman L, Breslow R. 2007. Oxidation potentials correlate with conductivities of aromatic molecular wires. Journal of the American Chemical Society. 129(41), 12376–12377.
Quinn, Jordan R., et al. “Oxidation Potentials Correlate with Conductivities of Aromatic Molecular Wires.” Journal of the American Chemical Society, vol. 129, no. 41, American Chemical Society, 2007, pp. 12376–77, doi:10.1021/ja0745097.
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PMID: 17887757
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