Structure formation and very low thermal conductivity in Pb:Te:Ag:Se mixtures

Drymiotis FR, Drye TB, Wang Y, He J, Rhodes D, Modic KA, Cawthorne S, Zhang QR. 2010. Structure formation and very low thermal conductivity in Pb:Te:Ag:Se mixtures. Journal of Applied Physics. 107(3), 033519.

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Journal Article | Published | English
Author
Drymiotis, Fivos R.; Drye, Tyler B.; Wang, Yisha; He, Jian; Rhodes, Daniel; Modic, Kimberly AISTA ; Cawthorne, Samantha; Zhang, Qiu Run
Abstract
We have observed that reacting Pb:Te:Ag:Se in a 1:1:1.9:1 molar ratio gives rise to what appears to be a predominantly single-phase alloy, which crystallizes in the PbSe cF8 fcc structure. However, further investigation of the structure using energy dispersive x-ray analysis reveals the presence of two phases, PbSe and β-Ag2Te, with identical lattice parameters. The total thermal conductivity of the formed alloy is remarkably low for a crystalline material, κT<0.6W∕mK at 675K, it is reproducible, and in addition, the compound has good mechanical properties.
Publishing Year
Date Published
2010-02-09
Journal Title
Journal of Applied Physics
Publisher
AIP
Volume
107
Issue
3
Article Number
033519
IST-REx-ID

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Drymiotis FR, Drye TB, Wang Y, et al. Structure formation and very low thermal conductivity in Pb:Te:Ag:Se mixtures. Journal of Applied Physics. 2010;107(3). doi:10.1063/1.3284946
Drymiotis, F. R., Drye, T. B., Wang, Y., He, J., Rhodes, D., Modic, K. A., … Zhang, Q. R. (2010). Structure formation and very low thermal conductivity in Pb:Te:Ag:Se mixtures. Journal of Applied Physics. AIP. https://doi.org/10.1063/1.3284946
Drymiotis, Fivos R., Tyler B. Drye, Yisha Wang, Jian He, Daniel Rhodes, Kimberly A Modic, Samantha Cawthorne, and Qiu Run Zhang. “Structure Formation and Very Low Thermal Conductivity in Pb:Te:Ag:Se Mixtures.” Journal of Applied Physics. AIP, 2010. https://doi.org/10.1063/1.3284946.
F. R. Drymiotis et al., “Structure formation and very low thermal conductivity in Pb:Te:Ag:Se mixtures,” Journal of Applied Physics, vol. 107, no. 3. AIP, 2010.
Drymiotis FR, Drye TB, Wang Y, He J, Rhodes D, Modic KA, Cawthorne S, Zhang QR. 2010. Structure formation and very low thermal conductivity in Pb:Te:Ag:Se mixtures. Journal of Applied Physics. 107(3), 033519.
Drymiotis, Fivos R., et al. “Structure Formation and Very Low Thermal Conductivity in Pb:Te:Ag:Se Mixtures.” Journal of Applied Physics, vol. 107, no. 3, 033519, AIP, 2010, doi:10.1063/1.3284946.

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