A site-selective and stereospecific cascade Suzuki–Miyaura annulation of alkyl 1,2-bisboronic esters and 2,2′-dihalo 1,1′-biaryls
Willems S, Toupalas G, Reisenbauer J, Morandi B. 2021. A site-selective and stereospecific cascade Suzuki–Miyaura annulation of alkyl 1,2-bisboronic esters and 2,2′-dihalo 1,1′-biaryls. Chemical Communications. 57(32), 3909–3912.
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Author
Willems, Suzanne;
Toupalas, Georgios;
Reisenbauer, Julia C.ISTA;
Morandi, Bill
Abstract
<p>A cascade Suzuki–Miyaura cross-coupling between two non-symmetrical coupling partners gave rise to 9,10-dihydrophenanthrenes with full site-selectivity. The choice of base was critical to facilitate the challenging coupling of the secondary boronate group.</p>
Publishing Year
Date Published
2021-03-15
Journal Title
Chemical Communications
Publisher
Royal Society of Chemistry
Volume
57
Issue
32
Page
3909-3912
ISSN
eISSN
IST-REx-ID
Cite this
Willems S, Toupalas G, Reisenbauer J, Morandi B. A site-selective and stereospecific cascade Suzuki–Miyaura annulation of alkyl 1,2-bisboronic esters and 2,2′-dihalo 1,1′-biaryls. Chemical Communications. 2021;57(32):3909-3912. doi:10.1039/d1cc00648g
Willems, S., Toupalas, G., Reisenbauer, J., & Morandi, B. (2021). A site-selective and stereospecific cascade Suzuki–Miyaura annulation of alkyl 1,2-bisboronic esters and 2,2′-dihalo 1,1′-biaryls. Chemical Communications. Royal Society of Chemistry. https://doi.org/10.1039/d1cc00648g
Willems, Suzanne, Georgios Toupalas, Julia Reisenbauer, and Bill Morandi. “A Site-Selective and Stereospecific Cascade Suzuki–Miyaura Annulation of Alkyl 1,2-Bisboronic Esters and 2,2′-Dihalo 1,1′-Biaryls.” Chemical Communications. Royal Society of Chemistry, 2021. https://doi.org/10.1039/d1cc00648g.
S. Willems, G. Toupalas, J. Reisenbauer, and B. Morandi, “A site-selective and stereospecific cascade Suzuki–Miyaura annulation of alkyl 1,2-bisboronic esters and 2,2′-dihalo 1,1′-biaryls,” Chemical Communications, vol. 57, no. 32. Royal Society of Chemistry, pp. 3909–3912, 2021.
Willems S, Toupalas G, Reisenbauer J, Morandi B. 2021. A site-selective and stereospecific cascade Suzuki–Miyaura annulation of alkyl 1,2-bisboronic esters and 2,2′-dihalo 1,1′-biaryls. Chemical Communications. 57(32), 3909–3912.
Willems, Suzanne, et al. “A Site-Selective and Stereospecific Cascade Suzuki–Miyaura Annulation of Alkyl 1,2-Bisboronic Esters and 2,2′-Dihalo 1,1′-Biaryls.” Chemical Communications, vol. 57, no. 32, Royal Society of Chemistry, 2021, pp. 3909–12, doi:10.1039/d1cc00648g.
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