Oxygen reactions in a non-aqueous Li+ electrolyte
Peng Z, Freunberger SA, Hardwick LJ, Chen Y, Giordani V, Bardé F, Novák P, Graham D, Tarascon J-M, Bruce PG. 2011. Oxygen reactions in a non-aqueous Li+ electrolyte. Angewandte Chemie International Edition. 50(28), 6351–6355.
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Journal Article
| Published
| English
Author
Peng, Zhangquan;
Freunberger, Stefan AlexanderISTA 
;
Hardwick, Laurence J.;
Chen, Yuhui;
Giordani, Vincent;
Bardé, Fanny;
Novák, Petr;
Graham, Duncan;
Tarascon, Jean-Marie;
Bruce, Peter G.
;
Hardwick, Laurence J.;
Chen, Yuhui;
Giordani, Vincent;
Bardé, Fanny;
Novák, Petr;
Graham, Duncan;
Tarascon, Jean-Marie;
Bruce, Peter G.Abstract
Spectroscopic data (see picture) provide direct evidence that in non‐aqueous Li+ electrolyte, O2 is reduced to O2−, which then forms LiO2 on the electrode surface which disproportionates to Li2O2. On charging, Li2O2 decomposes directly, in a one‐step reaction to evolve O2 and does not pass through LiO2 as an intermediate.
Publishing Year
Date Published
2011-07-04
Journal Title
Angewandte Chemie International Edition
Publisher
Wiley
Volume
50
Issue
28
Page
6351-6355
ISSN
IST-REx-ID
Cite this
Peng Z, Freunberger SA, Hardwick LJ, et al. Oxygen reactions in a non-aqueous Li+ electrolyte. Angewandte Chemie International Edition. 2011;50(28):6351-6355. doi:10.1002/anie.201100879
Peng, Z., Freunberger, S. A., Hardwick, L. J., Chen, Y., Giordani, V., Bardé, F., … Bruce, P. G. (2011). Oxygen reactions in a non-aqueous Li+ electrolyte. Angewandte Chemie International Edition. Wiley. https://doi.org/10.1002/anie.201100879
Peng, Zhangquan, Stefan Alexander Freunberger, Laurence J. Hardwick, Yuhui Chen, Vincent Giordani, Fanny Bardé, Petr Novák, Duncan Graham, Jean-Marie Tarascon, and Peter G. Bruce. “Oxygen Reactions in a Non-Aqueous Li+ Electrolyte.” Angewandte Chemie International Edition. Wiley, 2011. https://doi.org/10.1002/anie.201100879.
Z. Peng et al., “Oxygen reactions in a non-aqueous Li+ electrolyte,” Angewandte Chemie International Edition, vol. 50, no. 28. Wiley, pp. 6351–6355, 2011.
Peng Z, Freunberger SA, Hardwick LJ, Chen Y, Giordani V, Bardé F, Novák P, Graham D, Tarascon J-M, Bruce PG. 2011. Oxygen reactions in a non-aqueous Li+ electrolyte. Angewandte Chemie International Edition. 50(28), 6351–6355.
Peng, Zhangquan, et al. “Oxygen Reactions in a Non-Aqueous Li+ Electrolyte.” Angewandte Chemie International Edition, vol. 50, no. 28, Wiley, 2011, pp. 6351–55, doi:10.1002/anie.201100879.
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